<Li> Dr. Emilina Palmero (Sônia Braga) is Ray, Gloria, and Angie's deceased mother, George's mother - in - law, Vic's ex-wife, and Veronica, Carmen, and Max's grandmother . She is a dermatologist . She and Vic divorced after Vic discovered she was cheating on him . She only appears in one episode in which it is inferred that she is using Vic . Upon finding out about the affair, Angie tries to invite her over hoping she and Vic can reconcile and they could be a family again, but she cancels upon which Angie tells her mother she'll never forgive her for . When Vic announces to Emilina that he's engaged, she then insists that she wants to get back together begging him to take her back . In season six she and Vic were about to get back together right before she died . Emilina died in a heart attack . Angie's last conversation with her is reflected in the episode of her death . Emilina is mentioned often throughout the show by either Vic or George . George often uses Vic's situation with her to make him feel bad when he mocks him . </Li> <Li> Cecilia Lopez (Olga Merediz) is George and Linda's aunt, Manny's sister, and Benny's ex-sister in law . She hadn't seen Benny for a long time and in the second season she said she had lost touch with Manny two years before . When she bumped into Benny and George in a SuperStore, she was surprised to see Benny again (when Benny saw Cecilia she ran away) and happy to see George . She told George that his father was still alive, and came to his house to give him a photo of Manny holding the infant George . She appeared in the episode Who's your Daddy . </Li> <Li> Gloria Palmero (Jacqueline Obradors) is Vic and Emilina's daughter, Angie and Ray's sister, George and Claudia's sister - in - law, Carmen, Max and Veronica's aunt, Octavio and Lynette's niece . She was estranged with Angie until Angie's birthday . After announcing her divorce, she flirts with George and soon even attempts to hook up with him, kissing him in his garage (which Max witnesses through the door window leaving him shocked). Though its soon told that she only kissed him because she was jealous of Angie's loving relationship with him . After Angie finds out about what she did, she gets into a huge fight with her (with Angie telling George after the fight that "...and I gave her her hair back!") </Li> <Li> Ray Palmero (Andy García) is Angie and Gloria's brother, Vic's son, Claudia's ex-husband, Octavio and Lynette's nephew and Veronica's estranged father . He is known for conning family members and others out of money, most notably his father . He attempts to do the same with daughter Veronica's inheritance, but is stopped by George . He really does love his daughter, but is too messed - up to be a good father . It is possible he is in jail because George connected some road flares to a timer and put them in his suitcase which went off at the airport to get back at him for all the conning he has done over the years . </Li>

Angie's sister on the george lopez show