<Li> Judy Kuhn as singing voice of Pocahontas </Li> <Ul> <Li> Mel Gibson as John Smith, the love interest of Pocahontas . He is the only settler in Jamestown willing to befriend the natives due to his love for Pocahontas and acceptance of other cultures . John Pomeroy served as the supervising animator for John Smith . </Li> <Li> David Ogden Stiers as Governor Ratcliffe, the greedy and ruthlessly ambitious governor who leads an expedition to Virginia to find gold and other riches (which he wants to keep for himself). Unlike other Disney villains, he is based upon a combination of real - life historical figures . Duncan Marjoribanks served as the supervising animator for Ratcliffe . <Ul> <Li> Stiers also provided the voice of Wiggins, Ratcliffe's manservant . Chris Buck served as the supervising animator for Wiggins . </Li> </Ul> </Li> <Li> John Kassir as Meeko, Pocahontas's pet raccoon who is friendly to John Smith and loves eating . Nik Ranieri served as the supervising animator for Meeko . </Li> <Li> Russell Means as Chief Powhatan, Pocahontas's father and chief of the Powhatan . Ruben A. Aquino served as the supervising animator for Powhatan . </Li> </Ul> <Li> Mel Gibson as John Smith, the love interest of Pocahontas . He is the only settler in Jamestown willing to befriend the natives due to his love for Pocahontas and acceptance of other cultures . John Pomeroy served as the supervising animator for John Smith . </Li> <Li> David Ogden Stiers as Governor Ratcliffe, the greedy and ruthlessly ambitious governor who leads an expedition to Virginia to find gold and other riches (which he wants to keep for himself). Unlike other Disney villains, he is based upon a combination of real - life historical figures . Duncan Marjoribanks served as the supervising animator for Ratcliffe . <Ul> <Li> Stiers also provided the voice of Wiggins, Ratcliffe's manservant . Chris Buck served as the supervising animator for Wiggins . </Li> </Ul> </Li>

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