<P> HSAB concept is an initialism for "hard and soft (Lewis) acids and bases". Also known as the Pearson acid - base concept, HSAB is widely used in chemistry for explaining stability of compounds, reaction mechanisms and pathways . It assigns the terms' hard' or' soft', and' acid' or' base' to chemical species .' Hard' applies to species which are small, have high charge states (the charge criterion applies mainly to acids, to a lesser extent to bases), and are weakly polarizable .' Soft' applies to species which are big, have low charge states and are strongly polarizable . The concept is a way of applying the notion of orbital overlap to specific chemical cases . </P> <P> The theory is used in contexts where a qualitative, rather than quantitative, description would help in understanding the predominant factors which drive chemical properties and reactions . This is especially so in transition metal chemistry, where numerous experiments have been done to determine the relative ordering of ligands and transition metal ions in terms of their hardness and softness . </P>

Pearson theory of hard and soft acids and bases
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